Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation

[Image: see text] In the current paper, we successfully developed and used metal–organic frameworks (MOFs) based on MIL-101(Cr)-NH(2) with phosphorus acid functional groups MIL-101(Cr)-N(CH(2)PO(3)H(2))(2). The synthesized metal–organic frameworks (MOFs) as a multi-functional heterogeneous and nanop...

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Autores principales: Babaee, Saeed, Zarei, Mahmoud, Sepehrmansourie, Hassan, Zolfigol, Mohammad Ali, Rostamnia, Sadegh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7114146/
https://www.ncbi.nlm.nih.gov/pubmed/32258858
http://dx.doi.org/10.1021/acsomega.9b02133
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author Babaee, Saeed
Zarei, Mahmoud
Sepehrmansourie, Hassan
Zolfigol, Mohammad Ali
Rostamnia, Sadegh
author_facet Babaee, Saeed
Zarei, Mahmoud
Sepehrmansourie, Hassan
Zolfigol, Mohammad Ali
Rostamnia, Sadegh
author_sort Babaee, Saeed
collection PubMed
description [Image: see text] In the current paper, we successfully developed and used metal–organic frameworks (MOFs) based on MIL-101(Cr)-NH(2) with phosphorus acid functional groups MIL-101(Cr)-N(CH(2)PO(3)H(2))(2). The synthesized metal–organic frameworks (MOFs) as a multi-functional heterogeneous and nanoporous catalyst were used for the synthesis of N-amino-2-pyridone and pyrano [2,3-c]pyrazole derivatives via reaction of ethyl cyanoacetate or ethyl acetoacetate, hydrazine hydrate, malononitrile, and various aldehydes. The final step of the reaction mechanism was preceded by a cooperative vinylogous anomeric-based oxidation. Recycle and reusability of the described catalyst MIL-101(Cr)-N(CH(2)PO(3)H(2))(2) were also investigated.
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spelling pubmed-71141462020-04-03 Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation Babaee, Saeed Zarei, Mahmoud Sepehrmansourie, Hassan Zolfigol, Mohammad Ali Rostamnia, Sadegh ACS Omega [Image: see text] In the current paper, we successfully developed and used metal–organic frameworks (MOFs) based on MIL-101(Cr)-NH(2) with phosphorus acid functional groups MIL-101(Cr)-N(CH(2)PO(3)H(2))(2). The synthesized metal–organic frameworks (MOFs) as a multi-functional heterogeneous and nanoporous catalyst were used for the synthesis of N-amino-2-pyridone and pyrano [2,3-c]pyrazole derivatives via reaction of ethyl cyanoacetate or ethyl acetoacetate, hydrazine hydrate, malononitrile, and various aldehydes. The final step of the reaction mechanism was preceded by a cooperative vinylogous anomeric-based oxidation. Recycle and reusability of the described catalyst MIL-101(Cr)-N(CH(2)PO(3)H(2))(2) were also investigated. American Chemical Society 2020-03-20 /pmc/articles/PMC7114146/ /pubmed/32258858 http://dx.doi.org/10.1021/acsomega.9b02133 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Babaee, Saeed
Zarei, Mahmoud
Sepehrmansourie, Hassan
Zolfigol, Mohammad Ali
Rostamnia, Sadegh
Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title_full Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title_fullStr Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title_full_unstemmed Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title_short Synthesis of Metal–Organic Frameworks MIL-101(Cr)-NH(2) Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
title_sort synthesis of metal–organic frameworks mil-101(cr)-nh(2) containing phosphorous acid functional groups: application for the synthesis of n-amino-2-pyridone and pyrano [2,3-c]pyrazole derivatives via a cooperative vinylogous anomeric-based oxidation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7114146/
https://www.ncbi.nlm.nih.gov/pubmed/32258858
http://dx.doi.org/10.1021/acsomega.9b02133
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