Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy(2)O@C(72) and Dy(2)O@C(74) with fused pentagon pairs and flexible Dy–(μ(2)-O)–Dy angle

Dysprosium oxide clusterfullerenes Dy(2)O@C(s)(10528)–C(72) and Dy(2)O@C(2)(13333)–C(74) are synthesized and characterized by single-crystal X-ray diffraction. Carbon cages of both molecules feature two adjacent pentagon pairs. These pentalene units determine positions of endohedral Dy ions hence th...

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Detalles Bibliográficos
Autores principales: Velkos, Georgios, Yang, Wei, Yao, Yang-Rong, Sudarkova, Svetlana M., Liu, XinYe, Büchner, Bernd, Avdoshenko, Stanislav M., Chen, Ning, Popov, Alexey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7116574/
https://www.ncbi.nlm.nih.gov/pubmed/33437409
http://dx.doi.org/10.1039/d0sc00624f

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