Oxidation of Alkenes by Water with H(2) Liberation

[Image: see text] Oxidation by water with H(2) liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-ba...

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Autores principales: Tang, Shan, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7118709/
https://www.ncbi.nlm.nih.gov/pubmed/32182050
http://dx.doi.org/10.1021/jacs.0c01592
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author Tang, Shan
Ben-David, Yehoshoa
Milstein, David
author_facet Tang, Shan
Ben-David, Yehoshoa
Milstein, David
author_sort Tang, Shan
collection PubMed
description [Image: see text] Oxidation by water with H(2) liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-based PNP-Ru complex and indium(III) triflate. Compared to traditional Wacker-type oxidation, this transformation avoids the use of added chemical oxidants and liberates hydrogen gas as the only byproduct.
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spelling pubmed-71187092020-04-03 Oxidation of Alkenes by Water with H(2) Liberation Tang, Shan Ben-David, Yehoshoa Milstein, David J Am Chem Soc [Image: see text] Oxidation by water with H(2) liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-based PNP-Ru complex and indium(III) triflate. Compared to traditional Wacker-type oxidation, this transformation avoids the use of added chemical oxidants and liberates hydrogen gas as the only byproduct. American Chemical Society 2020-03-17 2020-04-01 /pmc/articles/PMC7118709/ /pubmed/32182050 http://dx.doi.org/10.1021/jacs.0c01592 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Tang, Shan
Ben-David, Yehoshoa
Milstein, David
Oxidation of Alkenes by Water with H(2) Liberation
title Oxidation of Alkenes by Water with H(2) Liberation
title_full Oxidation of Alkenes by Water with H(2) Liberation
title_fullStr Oxidation of Alkenes by Water with H(2) Liberation
title_full_unstemmed Oxidation of Alkenes by Water with H(2) Liberation
title_short Oxidation of Alkenes by Water with H(2) Liberation
title_sort oxidation of alkenes by water with h(2) liberation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7118709/
https://www.ncbi.nlm.nih.gov/pubmed/32182050
http://dx.doi.org/10.1021/jacs.0c01592
work_keys_str_mv AT tangshan oxidationofalkenesbywaterwithh2liberation
AT bendavidyehoshoa oxidationofalkenesbywaterwithh2liberation
AT milsteindavid oxidationofalkenesbywaterwithh2liberation

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