Crystal structures of trans-acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)(1,3,5-tri­aza-7-phosphaadamantane)molybdenum(II) and trans-acetyl­di­carbon­yl(η(5)-cyclo­penta­dien­yl)(3,7-diacetyl-1,3,7-tri­aza-5-phosphabi­cyclo­[3.3.1]nona­ne)molyb­den­um(II)

The title compounds, [Mo(C(5)H(5))(COCH(3))(C(6)H(12)N(3)P)(CO)(2)], (1), and [Mo(C(5)H(5))(COCH(3))(C(9)H(16)N(3)O(2)P)(C(6)H(5))(2)))(CO)(2)], (2), have been prepared by phosphine-induced migratory insertion from [Mo(C(5)H(5))(CO)(3)(CH(3))]. The mol­ecular structures of these complexes are quite...

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Detalles Bibliográficos
Autores principales: Anstey, Mitchell R., Bost, John L., Grumman, Anna S., Kennedy, Nicholas D., Whited, Matthew T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133026/
https://www.ncbi.nlm.nih.gov/pubmed/32280501
http://dx.doi.org/10.1107/S2056989020003679

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