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Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate
In the title hydrated complex, [Co(C(15)H(10)ClN(3))(2)]Cl(2)·4H(2)O, the complete dication is generated by [Image: see text] symmetry. The CoN(6) moiety shows distortion from regular octahedral geometry with the trans bond angles of two N—Co—N units being 160.62 (9)°. In the crystal, O—H⋯Cl and C—...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133030/ https://www.ncbi.nlm.nih.gov/pubmed/32280491 http://dx.doi.org/10.1107/S205698902000287X |
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| author | Thippeswamy, B. Suchetan, P. A. Mahadevan, K. M. Nagabhushana, H. Vijayakumar, G. R. |
| author_facet | Thippeswamy, B. Suchetan, P. A. Mahadevan, K. M. Nagabhushana, H. Vijayakumar, G. R. |
| author_sort | Thippeswamy, B. |
| collection | PubMed |
| description | In the title hydrated complex, [Co(C(15)H(10)ClN(3))(2)]Cl(2)·4H(2)O, the complete dication is generated by [Image: see text] symmetry. The CoN(6) moiety shows distortion from regular octahedral geometry with the trans bond angles of two N—Co—N units being 160.62 (9)°. In the crystal, O—H⋯Cl and C—H⋯O interactions link the components into (001) sheets. The title compound exhibits blue-light emission, as indicated by photoluminescence data, and a HOMO–LUMO energy separation of 2.23 eV was obtained from its diffuse reflectance spectrum. |
| format | Online Article Text |
| id | pubmed-7133030 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-71330302020-04-10 Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate Thippeswamy, B. Suchetan, P. A. Mahadevan, K. M. Nagabhushana, H. Vijayakumar, G. R. Acta Crystallogr E Crystallogr Commun Research Communications In the title hydrated complex, [Co(C(15)H(10)ClN(3))(2)]Cl(2)·4H(2)O, the complete dication is generated by [Image: see text] symmetry. The CoN(6) moiety shows distortion from regular octahedral geometry with the trans bond angles of two N—Co—N units being 160.62 (9)°. In the crystal, O—H⋯Cl and C—H⋯O interactions link the components into (001) sheets. The title compound exhibits blue-light emission, as indicated by photoluminescence data, and a HOMO–LUMO energy separation of 2.23 eV was obtained from its diffuse reflectance spectrum. International Union of Crystallography 2020-03-05 /pmc/articles/PMC7133030/ /pubmed/32280491 http://dx.doi.org/10.1107/S205698902000287X Text en © Thippeswamy et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Thippeswamy, B. Suchetan, P. A. Mahadevan, K. M. Nagabhushana, H. Vijayakumar, G. R. Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title | Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title_full | Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title_fullStr | Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title_full_unstemmed | Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title_short | Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate |
| title_sort | crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(ii) dichloride tetrahydrate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133030/ https://www.ncbi.nlm.nih.gov/pubmed/32280491 http://dx.doi.org/10.1107/S205698902000287X |
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