Crystal structure of 1,4,8,11-tetra­methyl-1,4,8,11-tetra­azonia­cyclo­tetra­decane bis­[chlorido­chromate(VI)] dichloride from synchrotron X-ray data

The crystal structure of title compound, (C(14)H(36)N(4))[CrO(3)Cl](2)Cl(2), has been determined by synchrotron radiation X-ray crystallography at 220 K. The macrocyclic cation lies across a crystallographic inversion center and hence the asymmetric unit contains one half of the organic cation, one chloro­chromate anion and one chloride anion. Both the Cl(−) anion and chloro­chromate Cl atom are involved in hydrogen bonding. In the crystal, hydrogen bonds involving the 1,4,8,11-tetra­methyl-1,4,8,11-tetra­azonia­cyclo­tetra­decane (TMC) N—H groups and C—H groups as donor groups and three O atoms of the chloro­chromate and the chloride anion as acceptor groups link the components, giving rise to a three-dimensional network.