A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis

The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH(4)[Mo(2)(C(6)H(11)O(6))O(5)]·H(2)O, was obtained from an attempt to pre...

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Detalles Bibliográficos
Autores principales: Mirzaei, Masoud, Tahmasebi, Morteza, Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133038/
https://www.ncbi.nlm.nih.gov/pubmed/32280496
http://dx.doi.org/10.1107/S2056989020002935
Descripción
Sumario:The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH(4)[Mo(2)(C(6)H(11)O(6))O(5)]·H(2)O, was obtained from an attempt to prepare a glutamic acid complex from the [Co(2)Mo(10)H(4)O(38)](6−) anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. A Hirshfeld surface analysis was also performed.

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