A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis

The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH(4)[Mo(2)(C(6)H(11)O(6))O(5)]·H(2)O, was obtained from an attempt to pre...

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Autores principales: Mirzaei, Masoud, Tahmasebi, Morteza, Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133038/
https://www.ncbi.nlm.nih.gov/pubmed/32280496
http://dx.doi.org/10.1107/S2056989020002935
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author Mirzaei, Masoud
Tahmasebi, Morteza
Mague, Joel T.
author_facet Mirzaei, Masoud
Tahmasebi, Morteza
Mague, Joel T.
author_sort Mirzaei, Masoud
collection PubMed
description The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH(4)[Mo(2)(C(6)H(11)O(6))O(5)]·H(2)O, was obtained from an attempt to prepare a glutamic acid complex from the [Co(2)Mo(10)H(4)O(38)](6−) anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. A Hirshfeld surface analysis was also performed.
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spelling pubmed-71330382020-04-10 A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis Mirzaei, Masoud Tahmasebi, Morteza Mague, Joel T. Acta Crystallogr E Crystallogr Commun Research Communications The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH(4)[Mo(2)(C(6)H(11)O(6))O(5)]·H(2)O, was obtained from an attempt to prepare a glutamic acid complex from the [Co(2)Mo(10)H(4)O(38)](6−) anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. A Hirshfeld surface analysis was also performed. International Union of Crystallography 2020-03-10 /pmc/articles/PMC7133038/ /pubmed/32280496 http://dx.doi.org/10.1107/S2056989020002935 Text en © Mirzaei et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Mirzaei, Masoud
Tahmasebi, Morteza
Mague, Joel T.
A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title_full A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title_fullStr A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title_full_unstemmed A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title_short A redetermination of the crystal structure of the mannitol complex NH(4)[Mo(2)O(5)(C(6)H(11)O(6))]·H(2)O: hydrogen-bonding scheme and Hirshfeld surface analysis
title_sort redetermination of the crystal structure of the mannitol complex nh(4)[mo(2)o(5)(c(6)h(11)o(6))]·h(2)o: hydrogen-bonding scheme and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7133038/
https://www.ncbi.nlm.nih.gov/pubmed/32280496
http://dx.doi.org/10.1107/S2056989020002935
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