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Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in Rh(II)-catalyzed X–H insertion reactions
N-Alkyl α-diazo-γ-butyrolactams, previously found to be unstable and to undergo unproductive dimerization to bishydrazones, were successfully converted immediately to various X–H insertion products with alcohols, aromatic amines and thiols via an in situ Rh(II)-catalyzed reaction. With aliphatic ami...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7136545/ https://www.ncbi.nlm.nih.gov/pubmed/32280388 http://dx.doi.org/10.3762/bjoc.16.55 |