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Copper-catalyzed O-alkenylation of phosphonates
Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phos...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7136550/ https://www.ncbi.nlm.nih.gov/pubmed/32280389 http://dx.doi.org/10.3762/bjoc.16.56 |
| _version_ | 1783518274619703296 |
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| author | Vázquez-Galiñanes, Nuria Andón-Rodríguez, Mariña Gómez-Roibás, Patricia Fañanás-Mastral, Martín |
| author_facet | Vázquez-Galiñanes, Nuria Andón-Rodríguez, Mariña Gómez-Roibás, Patricia Fañanás-Mastral, Martín |
| author_sort | Vázquez-Galiñanes, Nuria |
| collection | PubMed |
| description | Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields. |
| format | Online Article Text |
| id | pubmed-7136550 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-71365502020-04-10 Copper-catalyzed O-alkenylation of phosphonates Vázquez-Galiñanes, Nuria Andón-Rodríguez, Mariña Gómez-Roibás, Patricia Fañanás-Mastral, Martín Beilstein J Org Chem Letter Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields. Beilstein-Institut 2020-04-03 /pmc/articles/PMC7136550/ /pubmed/32280389 http://dx.doi.org/10.3762/bjoc.16.56 Text en Copyright © 2020, Vázquez-Galiñanes et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Letter Vázquez-Galiñanes, Nuria Andón-Rodríguez, Mariña Gómez-Roibás, Patricia Fañanás-Mastral, Martín Copper-catalyzed O-alkenylation of phosphonates |
| title | Copper-catalyzed O-alkenylation of phosphonates |
| title_full | Copper-catalyzed O-alkenylation of phosphonates |
| title_fullStr | Copper-catalyzed O-alkenylation of phosphonates |
| title_full_unstemmed | Copper-catalyzed O-alkenylation of phosphonates |
| title_short | Copper-catalyzed O-alkenylation of phosphonates |
| title_sort | copper-catalyzed o-alkenylation of phosphonates |
| topic | Letter |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7136550/ https://www.ncbi.nlm.nih.gov/pubmed/32280389 http://dx.doi.org/10.3762/bjoc.16.56 |
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