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Sustainable and Efficient Route for the Regeneration of Carbonyl Compounds from Oximes Using Aqueous Extract of Sapindus laurifolia under Microwave Radiation

[Image: see text] The synthesis of organic compounds using aqueous medium has become an indispensable tool for modern chemical synthesis strategies because of its ability to produce pure products with higher yield at ambient temperature. The conversion of oxime group into carbonyl group serves as a...

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Detalles Bibliográficos
Autores principales: Das, Debadutta, Mohapatra, Ranjan K., Parhi, Pankaj K., Sarangi, Ashish K., Sahu, Raghaba, Barik, Soumya R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144141/
https://www.ncbi.nlm.nih.gov/pubmed/32280915
http://dx.doi.org/10.1021/acsomega.0c00774
Descripción
Sumario:[Image: see text] The synthesis of organic compounds using aqueous medium has become an indispensable tool for modern chemical synthesis strategies because of its ability to produce pure products with higher yield at ambient temperature. The conversion of oxime group into carbonyl group serves as a key step for several organic syntheses. This article describes the regeneration of carbonyl compounds from the oxime group present in various carbon skeletons using I(2) and aqueous extract of Sapindus laurifolia under microwave radiation. A correlation has been established between the critical micellar concentration of saponin extracted from Sapindous laurifolia and the yield percentage of regenerated different carbonyl compounds. An effortless, competent, and environmentally compassionate protocol for the regeneration of carbonyl compound with a high percent of yield in the range 45–95% could be achieved.