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Kinetic Isotope Effects and Hydrogen Tunnelling in PCET Oxidations of Ascorbate: New Insights into Aqueous Chemistry?

Recent experimental studies of kinetic isotope effects (KIE-s) and hydrogen tunnelling comprising three proton-coupled electron transfer (PCET) oxidations of ascorbate monoanion, (a) in aqueous reaction solutions, (b) in the mixed water-organic cosolvent systems, (c) in aqueous solutions of various...

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Detalles Bibliográficos
Autores principales:	Karković Marković, Ana, Jakobušić Brala, Cvijeta, Pilepić, Viktor, Uršić, Stanko
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7144389/ https://www.ncbi.nlm.nih.gov/pubmed/32210039 http://dx.doi.org/10.3390/molecules25061443

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