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Chemo- and Regioselective Synthesis of Acyl-Cyclohexenes by a Tandem Acceptorless Dehydrogenation-[1,5]-Hydride Shift Cascade

[Image: see text] An atom-economical methodology to access substituted acyl-cyclohexenes from pentamethylacetophenone and 1,5-diols is described. This process is catalyzed by an iridium(I) catalyst in conjunction with a bulky electron rich phosphine ligand (CataCXium A) which favors acceptorless deh...

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Detalles Bibliográficos
Autores principales:	Smith, Lewis B., Armstrong, Roly J., Matheau-Raven, Daniel, Donohoe, Timothy J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7145340/ https://www.ncbi.nlm.nih.gov/pubmed/31967814 http://dx.doi.org/10.1021/jacs.9b12296

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