Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis

[Image: see text] One-pot processes for the synthesis of benzo[b]furans from 1-aryl- or 1-alkylketones using nonprecious transition metal catalysts have been developed. Regioselective iron(III)-catalyzed halogenation of the aryl ring, followed by iron- or copper-catalyzed O-arylation allowed the syn...

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Autores principales: Henry, Martyn C., Sutherland, Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7146889/
https://www.ncbi.nlm.nih.gov/pubmed/32186389
http://dx.doi.org/10.1021/acs.orglett.0c00754
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author Henry, Martyn C.
Sutherland, Andrew
author_facet Henry, Martyn C.
Sutherland, Andrew
author_sort Henry, Martyn C.
collection PubMed
description [Image: see text] One-pot processes for the synthesis of benzo[b]furans from 1-aryl- or 1-alkylketones using nonprecious transition metal catalysts have been developed. Regioselective iron(III)-catalyzed halogenation of the aryl ring, followed by iron- or copper-catalyzed O-arylation allowed the synthesis of various structural analogues, including the benzo[b]furan-derived natural products corsifuran C, moracin F, and caleprunin B.
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spelling pubmed-71468892020-04-13 Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis Henry, Martyn C. Sutherland, Andrew Org Lett [Image: see text] One-pot processes for the synthesis of benzo[b]furans from 1-aryl- or 1-alkylketones using nonprecious transition metal catalysts have been developed. Regioselective iron(III)-catalyzed halogenation of the aryl ring, followed by iron- or copper-catalyzed O-arylation allowed the synthesis of various structural analogues, including the benzo[b]furan-derived natural products corsifuran C, moracin F, and caleprunin B. American Chemical Society 2020-03-18 2020-04-03 /pmc/articles/PMC7146889/ /pubmed/32186389 http://dx.doi.org/10.1021/acs.orglett.0c00754 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Henry, Martyn C.
Sutherland, Andrew
Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title_full Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title_fullStr Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title_full_unstemmed Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title_short Synthesis of Benzo[b]furans by Intramolecular C–O Bond Formation Using Iron and Copper Catalysis
title_sort synthesis of benzo[b]furans by intramolecular c–o bond formation using iron and copper catalysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7146889/
https://www.ncbi.nlm.nih.gov/pubmed/32186389
http://dx.doi.org/10.1021/acs.orglett.0c00754
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