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Alkene Syn- and Anti-Oxyamination with Malonoyl Peroxides
[Image: see text] Malonoyl peroxide 6 is an effective reagent for the syn- or anti-oxyamination of alkenes. Reaction of 6 and an alkene in the presence of O-tert-butyl-N-tosylcarbamate (R(3) = CO(2)(t)Bu) leads to the anti-oxyaminated product in up to 99% yield. Use of O-methyl-N-tosyl carbamate (R(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7146911/ https://www.ncbi.nlm.nih.gov/pubmed/31999132 http://dx.doi.org/10.1021/acs.orglett.0c00253 |