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Rapid SPE – LC MS/MS analysis for atrazine, its by-products, simazine and S metolachlor in groundwater samples

A rapid analysis of pesticides using on-line Solid phase extraction LC MS/MS (Agilent Technology) was performed using only 2-mL water samples. SPE cartridge PLRP-s was used for the pre-concentration sample with methanol elution in back flush. Sensitive transitions and mass spectrometry conditions we...

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Detalles Bibliográficos
Autores principales: Blanchoud, Hélène, Alliot, Fabrice, Chen, Ningxin, Valdes, Danièle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7152673/
https://www.ncbi.nlm.nih.gov/pubmed/32300542
http://dx.doi.org/10.1016/j.mex.2020.100824
Descripción
Sumario:A rapid analysis of pesticides using on-line Solid phase extraction LC MS/MS (Agilent Technology) was performed using only 2-mL water samples. SPE cartridge PLRP-s was used for the pre-concentration sample with methanol elution in back flush. Sensitive transitions and mass spectrometry conditions were optimized by direct infusion of individual standard solutions in a positive electrospray mode. Water samples were spiked with internal standards to compensate the matrix effect. The limit of quantification was calculated to be 20 ng L(−1) • Only 2 mL water sample was used. • Samples were filtered at 0.2 µm and spiked with individual standard. • Compounds were separated in an 18.5-min elution time using the dynamic MRM program.