Constructing Core-Shell Co@N-Rich Carbon Additives Toward Enhanced Hydrogen Storage Performance of Magnesium Hydride

Magnesium hydride (MgH(2)) is regarded as a promising solid-state hydrogen storage material, on account of its moderate price and high gravimetric capacity. However, MgH(2)'s inferior kinetic of hydrogen release impedes its widespread application. In this work, we use core-shell Co@N-rich carbon (CoNC) additive as catalysts to ameliorate the performances of MgH(2). The surface morphologic structures and hydrogen desorption kinetics of different MgH(2)-CoNC composites are systematically studied. We find that MgH(2)-5 wt% CoNC with carbon contents of 17% (CoNC0) composites exhibit better hydrogen desorption performance. At 325°C, the MgH(2)-5 wt% CoNC0 composites can release up to 6.58 wt% of H(2) in 5 min, which is much higher than 0.3 wt% for pure MgH(2). Our results demonstrate that importing the core-shell structured catalysts can effectively enhance the hydrogen release kinetics.