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Stable Salts of Heteroleptic Iron Carbonyl/Nitrosyl Cations
The oxidation of Fe(CO)(5) with the [NO](+) salt of the weakly coordinating perfluoroalkoxyaluminate anion [F‐{Al(OR(F))(3)}(2)](−) (R(F)=C(CF(3))(3)) leads to stable salts of the 18 valence electron (VE) species [Fe(CO)(4)(NO)](+) and [Fe(CO)(NO)(3)](+) with the Enemark–Feltham numbers of {FeNO}(8)...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154531/ https://www.ncbi.nlm.nih.gov/pubmed/31846555 http://dx.doi.org/10.1002/anie.201915942 |