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Stable Mesoionic N‐Heterocyclic Olefins (mNHOs)

We report a new class of stable mesoionic N‐heterocyclic olefins, featuring a highly polarized (strongly ylidic) double bond. The ground‐state structure cannot be described through an uncharged mesomeric Lewis‐structure, thereby structurally distinguishing them from traditional N‐heterocyclic olefin...

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Detalles Bibliográficos
Autores principales: Hansmann, Max M., Antoni, Patrick W., Pesch, Henner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154647/
https://www.ncbi.nlm.nih.gov/pubmed/31863704
http://dx.doi.org/10.1002/anie.201914571

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