Cargando…

Cobalt‐Catalyzed Cross‐Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides

A combination of 10 % CoCl(2) and 20 % 2,2′‐bipyridine ligands enables cross‐coupling of functionalized primary and secondary alkylzinc reagents with various (hetero)aryl halides. Couplings with 1,3‐ and 1,4‐substituted cycloalkylzinc reagents proceeded diastereoselectively leading to functionalized...

Descripción completa

Detalles Bibliográficos
Autores principales:	Lutter, Ferdinand H., Grokenberger, Lucie, Spieß, Philipp, Hammann, Jeffrey M., Karaghiosoff, Konstantin, Knochel, Paul
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154687/ https://www.ncbi.nlm.nih.gov/pubmed/31909546 http://dx.doi.org/10.1002/anie.201914490

Ejemplares similares

Cobalt-catalyzed acylation-reactions of (hetero)arylzinc pivalates with thiopyridyl ester derivatives
por: Lutter, Ferdinand H., et al.
Publicado: (2019)

Stereoselective Csp(3)−Csp(2) Cross‐Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides
por: Skotnitzki, Juri, et al.
Publicado: (2019)

Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides
por: Yang, Yang, et al.
Publicado: (2014)

Cobalt-Catalyzed (Hetero)arylation of Saturated Cyclic Amines with Grignard Reagents
por: Barré, Baptiste, et al.
Publicado: (2018)

Cobalt-catalyzed aminocarbonylation of (hetero)aryl halides promoted by visible light
por: Veatch, Alexander M., et al.
Publicado: (2020)

Salt-stabilized alkylzinc pivalates: versatile reagents for cobalt-catalyzed selective 1,2-dialkylation
por: Lin, Jie, et al.
Publicado: (2023)

Highly selective nickel-catalyzed gem-difluoropropargylation of unactivated alkylzinc reagents
por: An, Lun, et al.
Publicado: (2017)

Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides
por: Asghar, Soneela, et al.
Publicado: (2017)

Copper-catalyzed arylation of alkyl halides with arylaluminum reagents
por: Shrestha, Bijay, et al.
Publicado: (2015)

Regioselective functionalization of aryl azoles as powerful tool for the synthesis of pharmaceutically relevant targets
por: Lutter, Ferdinand H., et al.
Publicado: (2020)

Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters
por: Echavarren, Javier, et al.
Publicado: (2019)

Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
por: Finck, Lucie, et al.
Publicado: (2022)

Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media
por: Cohen, Daniel T., et al.
Publicado: (2015)

Palladium-Catalyzed Hydroxycarbonylation of (Hetero)aryl Halides for DNA-Encoded Chemical Library Synthesis
por: Li, Jian-Yuan, et al.
Publicado: (2019)

A palladium-catalyzed synthesis of (hetero)aryl-substituted imidazoles from aryl halides, imines and carbon monoxide
por: Tjutrins, Jevgenijs, et al.
Publicado: (2017)

Iron-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Halides: A Competitive Hammett Study**
por: Hedström, Anna, et al.
Publicado: (2011)

Pd-catalyzed intramolecular addition of active methylene compounds to alkynes with subsequent cross-coupling with (hetero)aryl halides
por: Błocka, Aleksandra, et al.
Publicado: (2019)

Cu(II)-Catalyzed C-N Coupling of (Hetero)aryl Halides and N-Nucleophiles Promoted by α-Benzoin Oxime
por: Yuan, Chunling, et al.
Publicado: (2019)

Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations
por: Rousseau, Lidie, et al.
Publicado: (2020)

Radical–anion coupling through reagent design: hydroxylation of aryl halides
por: Greener, Andrew J., et al.
Publicado: (2021)

Prospects and Applications of Palladium Nanoparticles in the Cross‐coupling of (hetero)aryl Halides and Related Analogues
por: Ayogu, Jude I., et al.
Publicado: (2021)

Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel
por: Xu, Chang, et al.
Publicado: (2018)

Highly Regioselective Addition of Allylic Zinc Halides and Various Zinc Enolates to [1.1.1]Propellane
por: Schwärzer, Kuno, et al.
Publicado: (2020)

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides
por: Simonetti, Marco, et al.
Publicado: (2016)

Mechanistic Studies of the Palladium-Catalyzed Desulfinative Cross-Coupling of Aryl Bromides and (Hetero)Aryl Sulfinate Salts
por: de Gombert, Antoine, et al.
Publicado: (2020)

Efficient Pd‐Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents
por: Scherpf, Thorsten, et al.
Publicado: (2020)

Nickel-catalyzed asymmetric reductive arylation of α-chlorosulfones with aryl halides
por: Sun, Deli, et al.
Publicado: (2021)

Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
por: Sardzinski, Logan W., et al.
Publicado: (2015)

Nickel-catalyzed asymmetric reductive cross-coupling of α-chloroesters with (hetero)aryl iodides
por: DeLano, Travis J., et al.
Publicado: (2021)

Pyrrole‐Protected β‐Aminoalkylzinc Reagents for the Enantioselective Synthesis of Amino‐Derivatives
por: Leroux, Marcel, et al.
Publicado: (2020)

Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings
por: Martín, M. Trinidad, et al.
Publicado: (2021)

Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides
por: Huang, Liangbin, et al.
Publicado: (2016)

General stereoretentive preparation of chiral secondary mixed alkylmagnesium reagents and their use for enantioselective electrophilic aminations
por: Kremsmair, Alexander, et al.
Publicado: (2021)

Infrared Irradiation‐Assisted Solvent‐Free Pd‐Catalyzed (Hetero)aryl‐aryl Coupling via C−H Bond Activation
por: Albano, Gianluigi, et al.
Publicado: (2021)

Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions
por: Iwasaki, Takanori, et al.
Publicado: (2018)

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst
por: Friis, Stig D., et al.
Publicado: (2014)

δ C–H (hetero)arylation via Cu-catalyzed radical relay
por: Zhang, Zuxiao, et al.
Publicado: (2018)

Amide Synthesis by Nickel/Photoredox‐Catalyzed Direct Carbamoylation of (Hetero)Aryl Bromides
por: Alandini, Nurtalya, et al.
Publicado: (2020)

Cobalt Catalyst Determines Regioselectivity in Ring Opening of Epoxides with Aryl Halides
por: Potrząsaj, Aleksandra, et al.
Publicado: (2021)

Pd-catalyzed synthesis of 1-(hetero)aryl-2,2,2-trichloroethanols using chloral hydrate and (hetero)arylboroxines
por: Shimizu, Minori, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_03d6o0f6u90ultfvaph8d6ia28