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Catechol Thioesters: Ligands for Hierarchically Formed Lithium‐Bridged Titanium(IV) Helicates and Helicate‐Based Switches
The thioester moiety is introduced as a lithium binding unit for the hierarchical formation of titanium(IV) catecholate‐based lithium‐bridged helicates. In solution, the coordination compounds show a monomer–dimer equilibrium which —in comparison to the oxo esters— is significantly shifted towards t...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154688/ https://www.ncbi.nlm.nih.gov/pubmed/31899932 http://dx.doi.org/10.1002/chem.201905212 |