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Regio‐ and Stereoselective Thianthrenation of Olefins To Access Versatile Alkenyl Electrophiles

Herein, we report a regioselective alkenyl electrophile synthesis from unactivated olefins that is based on a direct and regioselective C−H thianthrenation reaction. The selectivity is proposed to arise from an unusual inverse‐electron‐demand hetero‐Diels–Alder reaction. The alkenyl sulfonium salts...

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Detalles Bibliográficos
Autores principales:	Chen, Junting, Li, Jiakun, Plutschack, Matthew B., Berger, Florian, Ritter, Tobias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7154751/ https://www.ncbi.nlm.nih.gov/pubmed/31782968 http://dx.doi.org/10.1002/anie.201914215

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