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In Situ Structural Determination of a Homogeneous Ruthenium Racemization Catalyst and Its Activated Intermediates Using X‐Ray Absorption Spectroscopy

The activation process of a known Ru‐catalyst, dicarbonyl(pentaphenylcyclopentadienyl)ruthenium chloride, has been studied in detail using time resolved in situ X‐ray absorption spectroscopy. The data provide bond lengths of the species involved in the process as well as information about bond forma...

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Detalles Bibliográficos
Autores principales: Gustafson, Karl P. J., Guðmundsson, Arnar, Bajnóczi, Éva G., Yuan, Ning, Zou, Xiaodong, Persson, Ingmar, Bäckvall, Jan‐E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155078/
https://www.ncbi.nlm.nih.gov/pubmed/31976570
http://dx.doi.org/10.1002/chem.201905479