Cooperative Catalysis for the Highly Diastereo‐ and Enantioselective [4+3]‐Cycloannulation of ortho‐Quinone Methides and Carbonyl Ylides

We describe herein a highly diastereo‐ and enantioselective [4+3]‐cycloannulation of ortho‐quinone methides and carbonyl ylides to furnish functionalized oxa‐bridged dibenzooxacines with excellent yields and stereoselectivity in a single synthetic step. The combination of rhodium and chiral phosphor...

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Detalles Bibliográficos
Autores principales: Suneja, Arun, Loui, Henning Jakob, Schneider, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155103/
https://www.ncbi.nlm.nih.gov/pubmed/31895488
http://dx.doi.org/10.1002/anie.201913603

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155103/
https://www.ncbi.nlm.nih.gov/pubmed/31895488
http://dx.doi.org/10.1002/anie.201913603

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