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Electron‐Rich, Lewis Acidic Diborane Meets N‐Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes

Herein reported are the reactions of an electron‐rich, Lewis acidic diborane with N‐heterocyclic aromatics to give first members of an unprecedented family of highly charged cationic cyclophanes with diboranyl units. Tetracationic cyclophanes with 4,4‘‐bipyridine/ 1,2‐bis(4‐pyridyl)ethylene and dibo...

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Detalles Bibliográficos
Autores principales: Widera, Anna, Filbeck, Erik, Wadepohl, Hubert, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7155121/
https://www.ncbi.nlm.nih.gov/pubmed/31943435
http://dx.doi.org/10.1002/chem.202000189