Raman and X-ray diffraction study of pressure-induced phase transition in synthetic Mg(2)TiO(4)

Synthetic Mg(2)TiO(4) qandilite was investigated to 50 and 40.4 GPa at room temperature using Raman spectroscopy and X-ray diffraction, respectively. The Raman measurements showed that cubic Mg(2)TiO(4) spinel transforms to a high pressure tetragonal (I4(1)/amd, No.141) phase at 14.7 GPa. Owing to sluggish kinetics at room temperature, the spinel phase coexists with the tetragonal phase between 14.7 and 24.3 GPa. In the X-ray diffraction experiment, transformation of the cubic Mg(2)TiO(4) to the tetragonal structure was complete by 29.2 GPa, ~5 GPa higher than the transition pressure obtained by Raman measurements, owing to slow kinetics. The obtained isothermal bulk modulus of Mg(2)TiO(4) spinel is K(T0) = 148(3) GPa when K(T0)’ = 6.6, or K(T0) = 166(1) GPa when K(T0)’ is fixed at 4. The isothermal bulk modulus of the high-pressure tetragonal phase is calculated to be 209(2) GPa and V(0) = 270(2) Å(3) when K(T0)’ is fixed at 4, and the volume reduction on change from cubic to tetragonal phase is about 9%. The calculated thermal Grüneisen parameters (γ(th)) of cubic and tetragonal Mg(2)TiO(4) phases are 1.01 and 0.63. Based on the radii ratio of spinel cations, a simple model is proposed to predict post-spinel structures.