Continuous Hydrogenation of Aqueous Furfural Using a Metal-Supported Activated Carbon Monolith

[Image: see text] Continuous hydrogenation of aqueous furfural (4.5%) was studied using a monolith form (ACM) of an activated carbon Pd catalyst (∼1.2% Pd). A sequential reaction pathway was observed, with ACM achieving high selectivity and space time yields (STYs) for furfuryl alcohol (∼25%, 60–70 g/L-cat/h, 7–15 1/h liquid hourly space velocity, LHSV), 2-methylfuran (∼25%, 45–50 g/L-cat/h, 7–15 1/h LHSV), and tetrahydrofurfuryl alcohol (∼20–60%, 10–50 g/L-cat/h, <7 1/h LHSV). ACM showed a low loss of activity and metal leaching over the course of the reactions and was not limited by H(2) external mass transfer resistance. Acetic acid (1%) did not significantly affect furfural conversion and product yields using ACM, suggesting Pd/ACM’s potential for conversion of crude furfural. Limited metal leaching combined with high metal dispersion and H(2) mass transfer rates in the composite carbon catalyst (ACM) provides possible advantages over granular and powdered forms in continuous processing.