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Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization
[Image: see text] Herein, we describe the synthesis of unsymmetrically substituted dibenzo[f,h]furazano[3,4-b]quinoxalines by intramolecular cyclization through direct transition metal-free C–H functionalization. The electrochemical and photophysical properties for several polycycles have been measu...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7161064/ https://www.ncbi.nlm.nih.gov/pubmed/32309730 http://dx.doi.org/10.1021/acsomega.0c00479 |
| _version_ | 1783522881969324032 |
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| author | Kvashnin, Yuriy A. Verbitskiy, Egor V. Eltsov, Oleg S. Slepukhin, Pavel A. Tameev, Alexey R. Nekrasova, Natalia V. Rusinov, Gennady L. Nunzi, Jean-Michel Chupakhin, Oleg N. Charushin, Valery N. |
| author_facet | Kvashnin, Yuriy A. Verbitskiy, Egor V. Eltsov, Oleg S. Slepukhin, Pavel A. Tameev, Alexey R. Nekrasova, Natalia V. Rusinov, Gennady L. Nunzi, Jean-Michel Chupakhin, Oleg N. Charushin, Valery N. |
| author_sort | Kvashnin, Yuriy A. |
| collection | PubMed |
| description | [Image: see text] Herein, we describe the synthesis of unsymmetrically substituted dibenzo[f,h]furazano[3,4-b]quinoxalines by intramolecular cyclization through direct transition metal-free C–H functionalization. The electrochemical and photophysical properties for several polycycles have been measured. In thin films of the dibenzo[f,h]furazano[3,4-b]quinoxalines, hole mobility is in the order of 10(–4) cm(2) V(–1) s(–1). The results show that the HOMO and LUMO energy levels are appropriate for using the compounds as hole-transport materials in thin-film devices, in particular, organic and perovskite solar cells. |
| format | Online Article Text |
| id | pubmed-7161064 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | American Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-71610642020-04-17 Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization Kvashnin, Yuriy A. Verbitskiy, Egor V. Eltsov, Oleg S. Slepukhin, Pavel A. Tameev, Alexey R. Nekrasova, Natalia V. Rusinov, Gennady L. Nunzi, Jean-Michel Chupakhin, Oleg N. Charushin, Valery N. ACS Omega [Image: see text] Herein, we describe the synthesis of unsymmetrically substituted dibenzo[f,h]furazano[3,4-b]quinoxalines by intramolecular cyclization through direct transition metal-free C–H functionalization. The electrochemical and photophysical properties for several polycycles have been measured. In thin films of the dibenzo[f,h]furazano[3,4-b]quinoxalines, hole mobility is in the order of 10(–4) cm(2) V(–1) s(–1). The results show that the HOMO and LUMO energy levels are appropriate for using the compounds as hole-transport materials in thin-film devices, in particular, organic and perovskite solar cells. American Chemical Society 2020-03-30 /pmc/articles/PMC7161064/ /pubmed/32309730 http://dx.doi.org/10.1021/acsomega.0c00479 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| spellingShingle | Kvashnin, Yuriy A. Verbitskiy, Egor V. Eltsov, Oleg S. Slepukhin, Pavel A. Tameev, Alexey R. Nekrasova, Natalia V. Rusinov, Gennady L. Nunzi, Jean-Michel Chupakhin, Oleg N. Charushin, Valery N. Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title | Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization
through Direct Transition Metal-Free C–H Functionalization
and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title_full | Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization
through Direct Transition Metal-Free C–H Functionalization
and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title_fullStr | Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization
through Direct Transition Metal-Free C–H Functionalization
and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title_full_unstemmed | Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization
through Direct Transition Metal-Free C–H Functionalization
and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title_short | Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization
through Direct Transition Metal-Free C–H Functionalization
and Electrochemical, Photophysical, and Charge Mobility Characterization |
| title_sort | dibenzo[f,h]furazano[3,4-b]quinoxalines: synthesis by intramolecular cyclization
through direct transition metal-free c–h functionalization
and electrochemical, photophysical, and charge mobility characterization |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7161064/ https://www.ncbi.nlm.nih.gov/pubmed/32309730 http://dx.doi.org/10.1021/acsomega.0c00479 |
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