Cargando…

Disordered hyperuniformity in two-dimensional amorphous silica

Disordered hyperuniformity (DHU) is a recently proposed new state of matter, which has been observed in a variety of classical and quantum many-body systems. DHU systems are characterized by vanishing infinite-wavelength normalized density fluctuations and are endowed with unique novel physical prop...

Descripción completa

Detalles Bibliográficos
Autores principales: Zheng, Yu, Liu, Lei, Nan, Hanqing, Shen, Zhen-Xiong, Zhang, Ge, Chen, Duyu, He, Lixin, Xu, Wenxiang, Chen, Mohan, Jiao, Yang, Zhuang, Houlong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7164937/
https://www.ncbi.nlm.nih.gov/pubmed/32494625
http://dx.doi.org/10.1126/sciadv.aba0826
_version_ 1783523384922996736
author Zheng, Yu
Liu, Lei
Nan, Hanqing
Shen, Zhen-Xiong
Zhang, Ge
Chen, Duyu
He, Lixin
Xu, Wenxiang
Chen, Mohan
Jiao, Yang
Zhuang, Houlong
author_facet Zheng, Yu
Liu, Lei
Nan, Hanqing
Shen, Zhen-Xiong
Zhang, Ge
Chen, Duyu
He, Lixin
Xu, Wenxiang
Chen, Mohan
Jiao, Yang
Zhuang, Houlong
author_sort Zheng, Yu
collection PubMed
description Disordered hyperuniformity (DHU) is a recently proposed new state of matter, which has been observed in a variety of classical and quantum many-body systems. DHU systems are characterized by vanishing infinite-wavelength normalized density fluctuations and are endowed with unique novel physical properties. Here, we report the discovery of disordered hyperuniformity in atomic-scale two-dimensional materials, i.e., amorphous silica composed of a single layer of atoms, based on spectral-density analysis of high-resolution transmission electron microscopy images. Moreover, we show via large-scale density functional theory calculations that DHU leads to almost complete closure of the electronic bandgap compared to the crystalline counterpart, making the material effectively a metal. This is in contrast to the conventional wisdom that disorder generally diminishes electronic transport and is due to the unique electron wave localization induced by the topological defects in the DHU state.
format Online
Article
Text
id pubmed-7164937
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Association for the Advancement of Science
record_format MEDLINE/PubMed
spelling pubmed-71649372020-06-02 Disordered hyperuniformity in two-dimensional amorphous silica Zheng, Yu Liu, Lei Nan, Hanqing Shen, Zhen-Xiong Zhang, Ge Chen, Duyu He, Lixin Xu, Wenxiang Chen, Mohan Jiao, Yang Zhuang, Houlong Sci Adv Research Articles Disordered hyperuniformity (DHU) is a recently proposed new state of matter, which has been observed in a variety of classical and quantum many-body systems. DHU systems are characterized by vanishing infinite-wavelength normalized density fluctuations and are endowed with unique novel physical properties. Here, we report the discovery of disordered hyperuniformity in atomic-scale two-dimensional materials, i.e., amorphous silica composed of a single layer of atoms, based on spectral-density analysis of high-resolution transmission electron microscopy images. Moreover, we show via large-scale density functional theory calculations that DHU leads to almost complete closure of the electronic bandgap compared to the crystalline counterpart, making the material effectively a metal. This is in contrast to the conventional wisdom that disorder generally diminishes electronic transport and is due to the unique electron wave localization induced by the topological defects in the DHU state. American Association for the Advancement of Science 2020-04-17 /pmc/articles/PMC7164937/ /pubmed/32494625 http://dx.doi.org/10.1126/sciadv.aba0826 Text en Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). http://creativecommons.org/licenses/by-nc/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (http://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Research Articles
Zheng, Yu
Liu, Lei
Nan, Hanqing
Shen, Zhen-Xiong
Zhang, Ge
Chen, Duyu
He, Lixin
Xu, Wenxiang
Chen, Mohan
Jiao, Yang
Zhuang, Houlong
Disordered hyperuniformity in two-dimensional amorphous silica
title Disordered hyperuniformity in two-dimensional amorphous silica
title_full Disordered hyperuniformity in two-dimensional amorphous silica
title_fullStr Disordered hyperuniformity in two-dimensional amorphous silica
title_full_unstemmed Disordered hyperuniformity in two-dimensional amorphous silica
title_short Disordered hyperuniformity in two-dimensional amorphous silica
title_sort disordered hyperuniformity in two-dimensional amorphous silica
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7164937/
https://www.ncbi.nlm.nih.gov/pubmed/32494625
http://dx.doi.org/10.1126/sciadv.aba0826
work_keys_str_mv AT zhengyu disorderedhyperuniformityintwodimensionalamorphoussilica
AT liulei disorderedhyperuniformityintwodimensionalamorphoussilica
AT nanhanqing disorderedhyperuniformityintwodimensionalamorphoussilica
AT shenzhenxiong disorderedhyperuniformityintwodimensionalamorphoussilica
AT zhangge disorderedhyperuniformityintwodimensionalamorphoussilica
AT chenduyu disorderedhyperuniformityintwodimensionalamorphoussilica
AT helixin disorderedhyperuniformityintwodimensionalamorphoussilica
AT xuwenxiang disorderedhyperuniformityintwodimensionalamorphoussilica
AT chenmohan disorderedhyperuniformityintwodimensionalamorphoussilica
AT jiaoyang disorderedhyperuniformityintwodimensionalamorphoussilica
AT zhuanghoulong disorderedhyperuniformityintwodimensionalamorphoussilica