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Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems

In the last decade, unceasing interest in atom transfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion or miniemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with...

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Detalles Bibliográficos
Autores principales: Surmacz, Karolina, Chmielarz, Paweł
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178667/
https://www.ncbi.nlm.nih.gov/pubmed/32268579
http://dx.doi.org/10.3390/ma13071717
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author Surmacz, Karolina
Chmielarz, Paweł
author_facet Surmacz, Karolina
Chmielarz, Paweł
author_sort Surmacz, Karolina
collection PubMed
description In the last decade, unceasing interest in atom transfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion or miniemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with the use of water as a dispersant. The main purpose of this review is to summarize ATRP methods used in emulsion media with different variants of initiating systems. A comparison of a dual over single catalytic approache by interfacial and ion pair catalysis is presented. In addition, future development directions for these methods are suggested for better use in biomedical and electronics industries.
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spelling pubmed-71786672020-04-28 Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems Surmacz, Karolina Chmielarz, Paweł Materials (Basel) Review In the last decade, unceasing interest in atom transfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion or miniemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with the use of water as a dispersant. The main purpose of this review is to summarize ATRP methods used in emulsion media with different variants of initiating systems. A comparison of a dual over single catalytic approache by interfacial and ion pair catalysis is presented. In addition, future development directions for these methods are suggested for better use in biomedical and electronics industries. MDPI 2020-04-06 /pmc/articles/PMC7178667/ /pubmed/32268579 http://dx.doi.org/10.3390/ma13071717 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Surmacz, Karolina
Chmielarz, Paweł
Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title_full Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title_fullStr Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title_full_unstemmed Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title_short Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems
title_sort low ppm atom transfer radical polymerization in (mini)emulsion systems
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178667/
https://www.ncbi.nlm.nih.gov/pubmed/32268579
http://dx.doi.org/10.3390/ma13071717
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