Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes

[Image: see text] Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)–Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 °C for 4 h under neat...

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Autores principales: Erken, Christina, Hindemith, Carsten, Weyhermüller, Thomas, Hölscher, Markus, Werlé, Christophe, Leitner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178791/
https://www.ncbi.nlm.nih.gov/pubmed/32337454
http://dx.doi.org/10.1021/acsomega.0c00562
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author Erken, Christina
Hindemith, Carsten
Weyhermüller, Thomas
Hölscher, Markus
Werlé, Christophe
Leitner, Walter
author_facet Erken, Christina
Hindemith, Carsten
Weyhermüller, Thomas
Hölscher, Markus
Werlé, Christophe
Leitner, Walter
author_sort Erken, Christina
collection PubMed
description [Image: see text] Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)–Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 °C for 4 h under neat conditions. Good to excellent yields could be obtained for a broad range of amines and alkynes.
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spelling pubmed-71787912020-04-24 Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes Erken, Christina Hindemith, Carsten Weyhermüller, Thomas Hölscher, Markus Werlé, Christophe Leitner, Walter ACS Omega [Image: see text] Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)–Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 °C for 4 h under neat conditions. Good to excellent yields could be obtained for a broad range of amines and alkynes. American Chemical Society 2020-04-01 /pmc/articles/PMC7178791/ /pubmed/32337454 http://dx.doi.org/10.1021/acsomega.0c00562 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Erken, Christina
Hindemith, Carsten
Weyhermüller, Thomas
Hölscher, Markus
Werlé, Christophe
Leitner, Walter
Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title_full Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title_fullStr Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title_full_unstemmed Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title_short Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
title_sort hydroamination of aromatic alkynes to imines catalyzed by pd(ii)–anthraphos complexes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7178791/
https://www.ncbi.nlm.nih.gov/pubmed/32337454
http://dx.doi.org/10.1021/acsomega.0c00562
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