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Protonated and Cationic Helium Clusters

Protonated rare gas clusters have previously been shown to display markably different structures compared to their pure, cationic counterparts. Here, we have performed high-resolution mass spectrometry measurements of protonated and pristine clusters of He containing up to 50 atoms. We identify nota...

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Detalles Bibliográficos
Autores principales: Lundberg, Linnea, Bartl, Peter, Leidlmair, Christian, Scheier, Paul, Gatchell, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7179179/
https://www.ncbi.nlm.nih.gov/pubmed/32120989
http://dx.doi.org/10.3390/molecules25051066
Descripción
Sumario:Protonated rare gas clusters have previously been shown to display markably different structures compared to their pure, cationic counterparts. Here, we have performed high-resolution mass spectrometry measurements of protonated and pristine clusters of He containing up to 50 atoms. We identify notable differences between the magic numbers present in the two types of clusters, but in contrast to heavier rare gas clusters, neither the protonated nor pure clusters exhibit signs of icosahedral symmetries. These findings are discussed in light of results from heavier rare gases and previous theoretical work on protonated helium.