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Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines

The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, ca...

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Autores principales: Araújo, Ana R. L., Tomé, Augusto C., Santos, Carla I. M., Faustino, Maria A. F., Neves, Maria G. P. M. S., Simões, Mário M. Q., Moura, Nuno M. M., Abu-Orabi, Sultan T., Cavaleiro, José A. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180445/
https://www.ncbi.nlm.nih.gov/pubmed/32290240
http://dx.doi.org/10.3390/molecules25071745
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author Araújo, Ana R. L.
Tomé, Augusto C.
Santos, Carla I. M.
Faustino, Maria A. F.
Neves, Maria G. P. M. S.
Simões, Mário M. Q.
Moura, Nuno M. M.
Abu-Orabi, Sultan T.
Cavaleiro, José A. S.
author_facet Araújo, Ana R. L.
Tomé, Augusto C.
Santos, Carla I. M.
Faustino, Maria A. F.
Neves, Maria G. P. M. S.
Simões, Mário M. Q.
Moura, Nuno M. M.
Abu-Orabi, Sultan T.
Cavaleiro, José A. S.
author_sort Araújo, Ana R. L.
collection PubMed
description The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step.
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spelling pubmed-71804452020-05-01 Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines Araújo, Ana R. L. Tomé, Augusto C. Santos, Carla I. M. Faustino, Maria A. F. Neves, Maria G. P. M. S. Simões, Mário M. Q. Moura, Nuno M. M. Abu-Orabi, Sultan T. Cavaleiro, José A. S. Molecules Review The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step. MDPI 2020-04-10 /pmc/articles/PMC7180445/ /pubmed/32290240 http://dx.doi.org/10.3390/molecules25071745 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Araújo, Ana R. L.
Tomé, Augusto C.
Santos, Carla I. M.
Faustino, Maria A. F.
Neves, Maria G. P. M. S.
Simões, Mário M. Q.
Moura, Nuno M. M.
Abu-Orabi, Sultan T.
Cavaleiro, José A. S.
Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_full Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_fullStr Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_full_unstemmed Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_short Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_sort azides and porphyrinoids: synthetic approaches and applications. part 2—azides, phthalocyanines, subphthalocyanines and porphyrazines
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180445/
https://www.ncbi.nlm.nih.gov/pubmed/32290240
http://dx.doi.org/10.3390/molecules25071745
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