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Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, ca...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180445/ https://www.ncbi.nlm.nih.gov/pubmed/32290240 http://dx.doi.org/10.3390/molecules25071745 |
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author | Araújo, Ana R. L. Tomé, Augusto C. Santos, Carla I. M. Faustino, Maria A. F. Neves, Maria G. P. M. S. Simões, Mário M. Q. Moura, Nuno M. M. Abu-Orabi, Sultan T. Cavaleiro, José A. S. |
author_facet | Araújo, Ana R. L. Tomé, Augusto C. Santos, Carla I. M. Faustino, Maria A. F. Neves, Maria G. P. M. S. Simões, Mário M. Q. Moura, Nuno M. M. Abu-Orabi, Sultan T. Cavaleiro, José A. S. |
author_sort | Araújo, Ana R. L. |
collection | PubMed |
description | The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step. |
format | Online Article Text |
id | pubmed-7180445 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-71804452020-05-01 Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines Araújo, Ana R. L. Tomé, Augusto C. Santos, Carla I. M. Faustino, Maria A. F. Neves, Maria G. P. M. S. Simões, Mário M. Q. Moura, Nuno M. M. Abu-Orabi, Sultan T. Cavaleiro, José A. S. Molecules Review The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step. MDPI 2020-04-10 /pmc/articles/PMC7180445/ /pubmed/32290240 http://dx.doi.org/10.3390/molecules25071745 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Araújo, Ana R. L. Tomé, Augusto C. Santos, Carla I. M. Faustino, Maria A. F. Neves, Maria G. P. M. S. Simões, Mário M. Q. Moura, Nuno M. M. Abu-Orabi, Sultan T. Cavaleiro, José A. S. Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_full | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_fullStr | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_full_unstemmed | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_short | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_sort | azides and porphyrinoids: synthetic approaches and applications. part 2—azides, phthalocyanines, subphthalocyanines and porphyrazines |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180445/ https://www.ncbi.nlm.nih.gov/pubmed/32290240 http://dx.doi.org/10.3390/molecules25071745 |
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