per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane

1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors.

Detalles Bibliográficos
Autores principales: Pearce, Nicholas, Davies, E. Stephen, Champness, Neil R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180461/
https://www.ncbi.nlm.nih.gov/pubmed/32252224
http://dx.doi.org/10.3390/molecules25071627
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author Pearce, Nicholas
Davies, E. Stephen
Champness, Neil R.
author_facet Pearce, Nicholas
Davies, E. Stephen
Champness, Neil R.
author_sort Pearce, Nicholas
collection PubMed
description 1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors.
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spelling pubmed-71804612020-05-01 per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane Pearce, Nicholas Davies, E. Stephen Champness, Neil R. Molecules Article 1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors. MDPI 2020-04-02 /pmc/articles/PMC7180461/ /pubmed/32252224 http://dx.doi.org/10.3390/molecules25071627 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pearce, Nicholas
Davies, E. Stephen
Champness, Neil R.
per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title_full per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title_fullStr per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title_full_unstemmed per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title_short per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane
title_sort per-alkoxy-pillar[5]arenes as electron donors: electrochemical properties of dimethoxy-pillar[5]arene and its corresponding rotaxane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180461/
https://www.ncbi.nlm.nih.gov/pubmed/32252224
http://dx.doi.org/10.3390/molecules25071627
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AT champnessneilr peralkoxypillar5arenesaselectrondonorselectrochemicalpropertiesofdimethoxypillar5areneanditscorrespondingrotaxane

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