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The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180810/ https://www.ncbi.nlm.nih.gov/pubmed/32252436 http://dx.doi.org/10.3390/molecules25071640 |
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author | Ali, Shimaa M. Eskandrani, Areej A. |
author_facet | Ali, Shimaa M. Eskandrani, Areej A. |
author_sort | Ali, Shimaa M. |
collection | PubMed |
description | La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ(max) of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye–surfactant complex. The adsorption efficiency of CTAB-capped La(0.9)Sr(0.1)FeO(3) was independent of the pH of the solution—equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, q(m), was 151.52 mg·g(−1), which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance. |
format | Online Article Text |
id | pubmed-7180810 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-71808102020-05-01 The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes Ali, Shimaa M. Eskandrani, Areej A. Molecules Article La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ(max) of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye–surfactant complex. The adsorption efficiency of CTAB-capped La(0.9)Sr(0.1)FeO(3) was independent of the pH of the solution—equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, q(m), was 151.52 mg·g(−1), which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance. MDPI 2020-04-02 /pmc/articles/PMC7180810/ /pubmed/32252436 http://dx.doi.org/10.3390/molecules25071640 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ali, Shimaa M. Eskandrani, Areej A. The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title | The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title_full | The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title_fullStr | The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title_full_unstemmed | The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title_short | The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes |
title_sort | sorption performance of cetyl trimethyl ammonium bromide-capped la(0.9)sr(0.1)feo(3) perovskite for organic pollutants from industrial processes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180810/ https://www.ncbi.nlm.nih.gov/pubmed/32252436 http://dx.doi.org/10.3390/molecules25071640 |
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