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The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes

La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the...

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Autores principales: Ali, Shimaa M., Eskandrani, Areej A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180810/
https://www.ncbi.nlm.nih.gov/pubmed/32252436
http://dx.doi.org/10.3390/molecules25071640
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author Ali, Shimaa M.
Eskandrani, Areej A.
author_facet Ali, Shimaa M.
Eskandrani, Areej A.
author_sort Ali, Shimaa M.
collection PubMed
description La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ(max) of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye–surfactant complex. The adsorption efficiency of CTAB-capped La(0.9)Sr(0.1)FeO(3) was independent of the pH of the solution—equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, q(m), was 151.52 mg·g(−1), which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance.
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spelling pubmed-71808102020-05-01 The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes Ali, Shimaa M. Eskandrani, Areej A. Molecules Article La(0.9)Sr(0.1)FeO(3) perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of λ(max) of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye–surfactant complex. The adsorption efficiency of CTAB-capped La(0.9)Sr(0.1)FeO(3) was independent of the pH of the solution—equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, q(m), was 151.52 mg·g(−1), which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance. MDPI 2020-04-02 /pmc/articles/PMC7180810/ /pubmed/32252436 http://dx.doi.org/10.3390/molecules25071640 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ali, Shimaa M.
Eskandrani, Areej A.
The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title_full The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title_fullStr The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title_full_unstemmed The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title_short The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La(0.9)Sr(0.1)FeO(3) Perovskite for Organic Pollutants from Industrial Processes
title_sort sorption performance of cetyl trimethyl ammonium bromide-capped la(0.9)sr(0.1)feo(3) perovskite for organic pollutants from industrial processes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7180810/
https://www.ncbi.nlm.nih.gov/pubmed/32252436
http://dx.doi.org/10.3390/molecules25071640
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