Cargando…

Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein

In this paper, the molecular connectivity indices were applied to theoretically predict the direct chemiluminescence (CL) behavior of chrysin and baicalein with our recently proposed discriminant function. Then, combined with flow-injection analysis, a new CL system for determination of chrysin and...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Baoxin, Guo, Lili, Xu, Chunli, Ma, Limei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier B.V. 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7185676/
https://www.ncbi.nlm.nih.gov/pubmed/18343187
http://dx.doi.org/10.1016/j.saa.2008.02.007
_version_ 1783526807338745856
author Li, Baoxin
Guo, Lili
Xu, Chunli
Ma, Limei
author_facet Li, Baoxin
Guo, Lili
Xu, Chunli
Ma, Limei
author_sort Li, Baoxin
collection PubMed
description In this paper, the molecular connectivity indices were applied to theoretically predict the direct chemiluminescence (CL) behavior of chrysin and baicalein with our recently proposed discriminant function. Then, combined with flow-injection analysis, a new CL system for determination of chrysin and baicalein was proposed. The method was based on the oxidation of chrysin and baicalein by acidic KMnO(4) in the presence of formaldehyde to produce strong CL emission. The present paper suggested a new model to discover new CL analytical system: first, to theoretical predict the CL behavior, and the second, to suggest analytical system.
format Online
Article
Text
id pubmed-7185676
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher Elsevier B.V.
record_format MEDLINE/PubMed
spelling pubmed-71856762020-04-28 Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein Li, Baoxin Guo, Lili Xu, Chunli Ma, Limei Spectrochim Acta A Mol Biomol Spectrosc Article In this paper, the molecular connectivity indices were applied to theoretically predict the direct chemiluminescence (CL) behavior of chrysin and baicalein with our recently proposed discriminant function. Then, combined with flow-injection analysis, a new CL system for determination of chrysin and baicalein was proposed. The method was based on the oxidation of chrysin and baicalein by acidic KMnO(4) in the presence of formaldehyde to produce strong CL emission. The present paper suggested a new model to discover new CL analytical system: first, to theoretical predict the CL behavior, and the second, to suggest analytical system. Elsevier B.V. 2008-12-01 2008-02-13 /pmc/articles/PMC7185676/ /pubmed/18343187 http://dx.doi.org/10.1016/j.saa.2008.02.007 Text en Copyright © 2008 Elsevier B.V. All rights reserved. Since January 2020 Elsevier has created a COVID-19 resource centre with free information in English and Mandarin on the novel coronavirus COVID-19. The COVID-19 resource centre is hosted on Elsevier Connect, the company's public news and information website. Elsevier hereby grants permission to make all its COVID-19-related research that is available on the COVID-19 resource centre - including this research content - immediately available in PubMed Central and other publicly funded repositories, such as the WHO COVID database with rights for unrestricted research re-use and analyses in any form or by any means with acknowledgement of the original source. These permissions are granted for free by Elsevier for as long as the COVID-19 resource centre remains active.
spellingShingle Article
Li, Baoxin
Guo, Lili
Xu, Chunli
Ma, Limei
Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title_full Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title_fullStr Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title_full_unstemmed Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title_short Flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
title_sort flow-injection chemiluminescence determination of chrysin and baicalein assisted by theoretical prediction of chemiluminescence behavior of chrysin and baicalein
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7185676/
https://www.ncbi.nlm.nih.gov/pubmed/18343187
http://dx.doi.org/10.1016/j.saa.2008.02.007
work_keys_str_mv AT libaoxin flowinjectionchemiluminescencedeterminationofchrysinandbaicaleinassistedbytheoreticalpredictionofchemiluminescencebehaviorofchrysinandbaicalein
AT guolili flowinjectionchemiluminescencedeterminationofchrysinandbaicaleinassistedbytheoreticalpredictionofchemiluminescencebehaviorofchrysinandbaicalein
AT xuchunli flowinjectionchemiluminescencedeterminationofchrysinandbaicaleinassistedbytheoreticalpredictionofchemiluminescencebehaviorofchrysinandbaicalein
AT malimei flowinjectionchemiluminescencedeterminationofchrysinandbaicaleinassistedbytheoreticalpredictionofchemiluminescencebehaviorofchrysinandbaicalein