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Assembling the prenylneoflavone system through a Pechmann condensation/Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis sequence
ABSTRACT: The multistep synthesis of a prenylneoflavone through a sequence of the Mitsunobu reaction/Claisen rearrangement/olefin cross-metathesis reaction has been accomplished in 5% yield over six steps starting from commercially available 3-methoxyacetophenone. The sequence is shown to be compati...
Autores principales: | Lozinski, Oleg A., Bistodeau, J., Bennetau-Pelissero, C., Khilya, Vladimir P., Shinkaruk, S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Vienna
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7186117/ https://www.ncbi.nlm.nih.gov/pubmed/32346184 http://dx.doi.org/10.1007/s00706-020-02584-8 |
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