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A Structurally Characterized Cobalt(I) σ‐Alkane Complex
A cobalt σ‐alkane complex, [Co(Cy(2)P(CH(2))(4)PCy(2))(norbornane)][BAr(F) (4)], was synthesized by a single‐crystal to single‐crystal solid/gas hydrogenation from a norbornadiene precursor, and its structure was determined by X‐ray crystallography. Magnetic data show this complex to be a triplet. P...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187152/ https://www.ncbi.nlm.nih.gov/pubmed/31943626 http://dx.doi.org/10.1002/anie.201914940 |
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| author | Boyd, Timothy M. Tegner, Bengt E. Tizzard, Graham J. Martínez‐Martínez, Antonio J. Neale, Samuel E. Hayward, Michael A. Coles, Simon J. Macgregor, Stuart A. Weller, Andrew S. |
| author_facet | Boyd, Timothy M. Tegner, Bengt E. Tizzard, Graham J. Martínez‐Martínez, Antonio J. Neale, Samuel E. Hayward, Michael A. Coles, Simon J. Macgregor, Stuart A. Weller, Andrew S. |
| author_sort | Boyd, Timothy M. |
| collection | PubMed |
| description | A cobalt σ‐alkane complex, [Co(Cy(2)P(CH(2))(4)PCy(2))(norbornane)][BAr(F) (4)], was synthesized by a single‐crystal to single‐crystal solid/gas hydrogenation from a norbornadiene precursor, and its structure was determined by X‐ray crystallography. Magnetic data show this complex to be a triplet. Periodic DFT and electronic structure analyses revealed weak C−H→Co σ‐interactions, augmented by dispersive stabilization between the alkane ligand and the anion microenvironment. The calculations are most consistent with a η(1):η(1)‐alkane binding mode. |
| format | Online Article Text |
| id | pubmed-7187152 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-71871522020-04-28 A Structurally Characterized Cobalt(I) σ‐Alkane Complex Boyd, Timothy M. Tegner, Bengt E. Tizzard, Graham J. Martínez‐Martínez, Antonio J. Neale, Samuel E. Hayward, Michael A. Coles, Simon J. Macgregor, Stuart A. Weller, Andrew S. Angew Chem Int Ed Engl Communications A cobalt σ‐alkane complex, [Co(Cy(2)P(CH(2))(4)PCy(2))(norbornane)][BAr(F) (4)], was synthesized by a single‐crystal to single‐crystal solid/gas hydrogenation from a norbornadiene precursor, and its structure was determined by X‐ray crystallography. Magnetic data show this complex to be a triplet. Periodic DFT and electronic structure analyses revealed weak C−H→Co σ‐interactions, augmented by dispersive stabilization between the alkane ligand and the anion microenvironment. The calculations are most consistent with a η(1):η(1)‐alkane binding mode. John Wiley and Sons Inc. 2020-02-20 2020-04-06 /pmc/articles/PMC7187152/ /pubmed/31943626 http://dx.doi.org/10.1002/anie.201914940 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Communications Boyd, Timothy M. Tegner, Bengt E. Tizzard, Graham J. Martínez‐Martínez, Antonio J. Neale, Samuel E. Hayward, Michael A. Coles, Simon J. Macgregor, Stuart A. Weller, Andrew S. A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title | A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title_full | A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title_fullStr | A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title_full_unstemmed | A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title_short | A Structurally Characterized Cobalt(I) σ‐Alkane Complex |
| title_sort | structurally characterized cobalt(i) σ‐alkane complex |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187152/ https://www.ncbi.nlm.nih.gov/pubmed/31943626 http://dx.doi.org/10.1002/anie.201914940 |
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