Cargando…

A Structurally Characterized Cobalt(I) σ‐Alkane Complex

A cobalt σ‐alkane complex, [Co(Cy(2)P(CH(2))(4)PCy(2))(norbornane)][BAr(F) (4)], was synthesized by a single‐crystal to single‐crystal solid/gas hydrogenation from a norbornadiene precursor, and its structure was determined by X‐ray crystallography. Magnetic data show this complex to be a triplet. P...

Descripción completa

Detalles Bibliográficos
Autores principales:	Boyd, Timothy M., Tegner, Bengt E., Tizzard, Graham J., Martínez‐Martínez, Antonio J., Neale, Samuel E., Hayward, Michael A., Coles, Simon J., Macgregor, Stuart A., Weller, Andrew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187152/ https://www.ncbi.nlm.nih.gov/pubmed/31943626 http://dx.doi.org/10.1002/anie.201914940

Ejemplares similares

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes
por: McKay, Alasdair I., et al.
Publicado: (2019)

A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane
por: Bukvic, Alexander J., et al.
Publicado: (2021)

Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State
por: Furfari, Samantha K., et al.
Publicado: (2021)

Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex
por: Doyle, Laurence R., et al.
Publicado: (2022)

MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF(5))(2)C(6)H(3))(4)](−) anion, via on-grid solid/gas single-crystal to single-crystal reactivity
por: Doyle, Laurence R., et al.
Publicado: (2022)

A Rhodium–Pentane Sigma‐Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques
por: Chadwick, F. Mark, et al.
Publicado: (2016)

Chlorocobalt complexes with pyridylethyl-derived diazacycloalkanes
por: Addison, Anthony W., et al.
Publicado: (2022)

Alternative σ(I)/anti-σ(I) factors represent a unique form of bacterial σ/anti-σ complex
por: Wei, Zhen, et al.
Publicado: (2019)

Stereoselective Alkane Oxidation with meta-Chloroperoxybenzoic Acid (MCPBA) Catalyzed by Organometallic Cobalt Complexes †
por: Shul’pin, Georgiy B., et al.
Publicado: (2016)

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism
por: Perutz, Robin N., et al.
Publicado: (2021)

Identification and use of an alkane transporter plug-in for applications in biocatalysis and whole-cell biosensing of alkanes
por: Grant, Chris, et al.
Publicado: (2014)

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)

Dehydropolymerization of H(3)B·NMeH(2) Mediated by Cationic Iridium(III) Precatalysts Bearing κ(3)-(i)Pr-PN(R)P Pincer Ligands (R = H, Me): An Unexpected Inner-Sphere Mechanism
por: Brodie, Claire N., et al.
Publicado: (2022)

Evolution of a σ–(c-di-GMP)–anti-σ switch
por: Schumacher, Maria A., et al.
Publicado: (2021)

The σ enigma: Bacterial σ factors, archaeal TFB and eukaryotic TFIIB are homologs
por: Burton, Samuel P, et al.
Publicado: (2014)

On the Nature of σ–σ, σ–π, and π–π Stacking in Extended Systems
por: Cabaleiro-Lago, Enrique M., et al.
Publicado: (2018)

Structural insights into diversity and n-alkane biodegradation mechanisms of alkane hydroxylases
por: Ji, Yurui, et al.
Publicado: (2013)

London Dispersion in Alkane Solvents
por: Strauss, Marcel A., et al.
Publicado: (2020)

Multifactorial control of the expression of a CRISPR-Cas system by an extracytoplasmic function σ/anti-σ pair and a global regulatory complex
por: Bernal-Bernal, Diego, et al.
Publicado: (2018)

Cobalt-catalyzed C(sp(3))–H/C(sp(2))–H oxidative coupling between alkanes and benzamides
por: Li, Shuangjie, et al.
Publicado: (2018)

Synergistic effects of inhibiting the MNK-eIF4E and PI3K/AKT/ mTOR pathways on cell migration in MDA-MB-231 cells
por: Lineham, Ella, et al.
Publicado: (2018)

The Bifurcated σ-Hole···σ-Hole Stacking Interactions
por: Zhang, Yu, et al.
Publicado: (2022)

A–X⋯σ Interactions—Halogen Bonds with σ-Electrons as the Lewis Base Centre
por: Grabowski, Sławomir J.
Publicado: (2021)

Biochemical studies on the metabolic activation of halogenated alkanes.
por: Cheeseman, K H, et al.
Publicado: (1985)

Corksorb Enhances Alkane Degradation by Hydrocarbonoclastic Bacteria
por: Martins, Valdo R., et al.
Publicado: (2021)

Structure of the transcription open complex of distinct σ(I) factors
por: Li, Jie, et al.
Publicado: (2023)

Study of Σ-hyperonic atoms.
por: Backenstoss, Gerhard, et al.
Publicado: (1973)

Synthesis and characterisation of cobalt, nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes
por: Tordin, Elisa, et al.
Publicado: (2013)

Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes
por: Hu, Ming, et al.
Publicado: (2020)

Measurement of the cross-section ratio σ$_{ψ(2S)}$/σ$_{J/ψ(1S)}$ in exclusive photoproduction at HERA
por: Abt, I., et al.
Publicado: (2022)

Structural basis for extracellular cis and trans RPTPσ signal competition in synaptogenesis
por: Coles, Charlotte H., et al.
Publicado: (2014)

Copper‐Catalyzed Dehydrogenative Amidation of Light Alkanes
por: Fuentes, M. Ángeles, et al.
Publicado: (2021)

Unconventional Type III Halogen···Halogen Interactions: A Quantum Mechanical Elucidation of σ-Hole···σ-Hole and Di-σ-Hole Interactions
por: Ibrahim, Mahmoud A. A., et al.
Publicado: (2020)

Synthesis and Structural Characterization of Copper Complexes Containing “R-Substituted” Bis-7-Azaindolyl Borate Ligands
por: Jackson, Miriam, et al.
Publicado: (2023)

Catalytic Hydrogenolysis of Polyolefins into Alkanes
por: Sánchez-Rivera, Kevin L., et al.
Publicado: (2020)

Insights into cyanobacterial alkane biosynthesis
por: Parveen, Humaira, et al.
Publicado: (2021)

The Activity of the Pseudomonas aeruginosa Virulence Regulator σ(VreI) Is Modulated by the Anti-σ Factor VreR and the Transcription Factor PhoB
por: Quesada, Jose M., et al.
Publicado: (2016)

Transcriptome response to alkane biofuels in Saccharomyces cerevisiae: identification of efflux pumps involved in alkane tolerance
por: Ling, Hua, et al.
Publicado: (2013)

Fe(III) in the high-spin state in dimethylammonium bis[3-ethoxysalicylaldehyde thiosemicarbazonato(2–)-κ(3) O (2),N (1),S]ferrate(III)
por: Powell, Robyn E., et al.
Publicado: (2023)

Synthesis and solid-state characterisation of 4-substituted methylidene oxindoles
por: Tizzard, Graham J, et al.
Publicado: (2013)

Cannot write session to /tmp/vufind_sessions/sess_hq2m9r7g7ubagte0s7rcebjjhv