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Sodium Bicyclo[1.1.1]pentanesulfinate: A Bench‐Stable Precursor for Bicyclo[1.1.1]pentylsulfones and Bicyclo‐ [1.1.1]pentanesulfonamides

Herein, we present the synthesis of the bench‐stable sodium bicyclo[1.1.1]pentanesulfinate (BCP‐SO(2)Na) and its application in the synthesis of bicyclo[1.1.1]pentyl (BCP) sulfones and sulfonamides. The salt can be obtained in a four‐step procedure from commercially available precursors in multigram...

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Detalles Bibliográficos
Autores principales: Bär, Robin M., Gross, Patrick J., Nieger, Martin, Bräse, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187227/
https://www.ncbi.nlm.nih.gov/pubmed/31922305
http://dx.doi.org/10.1002/chem.202000097