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Solvate‐Induced Semiconductor to Metal Transition: Flat [Formula: see text] [Bi(1−)] Zigzag Chains in Metallic KBi⋅NH(3) versus [Formula: see text] [Bi(1−)] Helices in Semiconducting KBi

Polymeric [Formula: see text] [Bi](−) in KBi⋅NH(3) has planar zigzag chains with two‐connected Bi atoms and metallic properties, whereas KBi, which has helical chains of Bi atoms, is semiconducting. The isomerization of the Bi chain is induced by solvate molecules. In the novel layered solvate struc...

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Detalles Bibliográficos
Autores principales:	Mayer, Kerstin, Dums, Jasmin V., Benda, Christian B., Klein, Wilhelm, Fässler, Thomas F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7187340/ https://www.ncbi.nlm.nih.gov/pubmed/31917887 http://dx.doi.org/10.1002/anie.201915735

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