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NaCl substrates for high temperature processing and transfer of ultrathin materials

Ultrathin materials often require high temperatures for growth and processing, which cannot be withstood by the substrate underneath. For example, polymers are widely used as a supporting layer but unfortunately have low strain-point temperatures. This is the case of polyethylene terephthalate (PET)...

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Autores principales: Graham, Christina, Frances, Miriam Marchena Martin, Maniyara, Rinu Abraham, Wen, Yugeng, Mazumder, Prantik, Pruneri, Valerio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7190726/
https://www.ncbi.nlm.nih.gov/pubmed/32350348
http://dx.doi.org/10.1038/s41598-020-64313-9
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author Graham, Christina
Frances, Miriam Marchena Martin
Maniyara, Rinu Abraham
Wen, Yugeng
Mazumder, Prantik
Pruneri, Valerio
author_facet Graham, Christina
Frances, Miriam Marchena Martin
Maniyara, Rinu Abraham
Wen, Yugeng
Mazumder, Prantik
Pruneri, Valerio
author_sort Graham, Christina
collection PubMed
description Ultrathin materials often require high temperatures for growth and processing, which cannot be withstood by the substrate underneath. For example, polymers are widely used as a supporting layer but unfortunately have low strain-point temperatures. This is the case of polyethylene terephthalate (PET) which has glass transition and melting temperatures of 76 and 250 °C, respectively. In this paper we propose to use polished salt, a material that can withstand high temperatures during fabrication and, at the same time, can be sacrificed during the transfer onto the final substrates. More specifically, we demonstrate thermal dewetting of Au ultrathin metal films and growth of MoS(2) on NaCl at 750 and 650 °C, respectively, and subsequent transfer onto PET films, after which the salt is easily dissolved by water. We believe that the proposed technique can be extended to fabrication of other ultrathin materials, e.g. graphene, as well as final substrates for a wide range of applications, including flexible electronic and optoelectronic devices.
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spelling pubmed-71907262020-05-05 NaCl substrates for high temperature processing and transfer of ultrathin materials Graham, Christina Frances, Miriam Marchena Martin Maniyara, Rinu Abraham Wen, Yugeng Mazumder, Prantik Pruneri, Valerio Sci Rep Article Ultrathin materials often require high temperatures for growth and processing, which cannot be withstood by the substrate underneath. For example, polymers are widely used as a supporting layer but unfortunately have low strain-point temperatures. This is the case of polyethylene terephthalate (PET) which has glass transition and melting temperatures of 76 and 250 °C, respectively. In this paper we propose to use polished salt, a material that can withstand high temperatures during fabrication and, at the same time, can be sacrificed during the transfer onto the final substrates. More specifically, we demonstrate thermal dewetting of Au ultrathin metal films and growth of MoS(2) on NaCl at 750 and 650 °C, respectively, and subsequent transfer onto PET films, after which the salt is easily dissolved by water. We believe that the proposed technique can be extended to fabrication of other ultrathin materials, e.g. graphene, as well as final substrates for a wide range of applications, including flexible electronic and optoelectronic devices. Nature Publishing Group UK 2020-04-29 /pmc/articles/PMC7190726/ /pubmed/32350348 http://dx.doi.org/10.1038/s41598-020-64313-9 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Graham, Christina
Frances, Miriam Marchena Martin
Maniyara, Rinu Abraham
Wen, Yugeng
Mazumder, Prantik
Pruneri, Valerio
NaCl substrates for high temperature processing and transfer of ultrathin materials
title NaCl substrates for high temperature processing and transfer of ultrathin materials
title_full NaCl substrates for high temperature processing and transfer of ultrathin materials
title_fullStr NaCl substrates for high temperature processing and transfer of ultrathin materials
title_full_unstemmed NaCl substrates for high temperature processing and transfer of ultrathin materials
title_short NaCl substrates for high temperature processing and transfer of ultrathin materials
title_sort nacl substrates for high temperature processing and transfer of ultrathin materials
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7190726/
https://www.ncbi.nlm.nih.gov/pubmed/32350348
http://dx.doi.org/10.1038/s41598-020-64313-9
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