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Controlling the nonadiabatic electron-transfer reaction rate through molecular-vibration polaritons in the ultrastrong coupling regime

Recent experiments showed that the chemical reaction rate is modified, either increased or decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical cavity. Herein we investigate how the rate of an electron-transfer reaction depends on the molecule-cavity coupling in...

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Detalles Bibliográficos
Autores principales: Phuc, Nguyen Thanh, Trung, Pham Quang, Ishizaki, Akihito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7193605/
https://www.ncbi.nlm.nih.gov/pubmed/32355233
http://dx.doi.org/10.1038/s41598-020-62899-8