MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid

Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h(−1)...

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Autores principales: Ortega-Murcia, Alejandro, Navlani-García, Miriam, Morallón, Emilia, Cazorla-Amorós, Diego
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199183/
https://www.ncbi.nlm.nih.gov/pubmed/32411676
http://dx.doi.org/10.3389/fchem.2020.00359
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author Ortega-Murcia, Alejandro
Navlani-García, Miriam
Morallón, Emilia
Cazorla-Amorós, Diego
author_facet Ortega-Murcia, Alejandro
Navlani-García, Miriam
Morallón, Emilia
Cazorla-Amorós, Diego
author_sort Ortega-Murcia, Alejandro
collection PubMed
description Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h(−1) at 80°C. The presence of PVP was shown to play a positive role by increasing the hydrophilicity of the materials and enhancing the interface contact between the reactant molecules and the catalytic active sites.
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spelling pubmed-71991832020-05-14 MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid Ortega-Murcia, Alejandro Navlani-García, Miriam Morallón, Emilia Cazorla-Amorós, Diego Front Chem Chemistry Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h(−1) at 80°C. The presence of PVP was shown to play a positive role by increasing the hydrophilicity of the materials and enhancing the interface contact between the reactant molecules and the catalytic active sites. Frontiers Media S.A. 2020-04-28 /pmc/articles/PMC7199183/ /pubmed/32411676 http://dx.doi.org/10.3389/fchem.2020.00359 Text en Copyright © 2020 Ortega-Murcia, Navlani-García, Morallón and Cazorla-Amorós. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Ortega-Murcia, Alejandro
Navlani-García, Miriam
Morallón, Emilia
Cazorla-Amorós, Diego
MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title_full MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title_fullStr MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title_full_unstemmed MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title_short MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
title_sort mwcnt-supported pvp-capped pd nanoparticles as efficient catalysts for the dehydrogenation of formic acid
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199183/
https://www.ncbi.nlm.nih.gov/pubmed/32411676
http://dx.doi.org/10.3389/fchem.2020.00359
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