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Synthesis and crystal structure of a penta­copper(II) 12-metallacrown-4: cis-di­aqua­tetra­kis­(di­methyl­formamide-κO)manganese(II) tetra­kis­(μ(3)-N,2-dioxido­benzene-1-carboximidate)penta­copper(II) di­methyl­formamide monosolvate

The title compound, [Mn(C(3)H(7)NO)(4)(H(2)O)(2)][Cu(5)(C(7)H(4)NO(3))(4)]·C(3)H(7)NO or cis-[Mn(H(2)O)(2)(DMF)(4)]{Cu[12-MC(Cu(II)N(shi))-4]}·DMF, where MC is metallacrown, shi(3−) is salicyl­hydroximate, and DMF is N,N-di­methyl­formamide, crystallizes in the monoclinic space group P2(1)/n. Two cr...

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Detalles Bibliográficos
Autores principales: Van Trieste III, Gerard P., Zeller, Matthias, Zaleski, Curtis M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199261/
https://www.ncbi.nlm.nih.gov/pubmed/32431945
http://dx.doi.org/10.1107/S2056989020005770