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Synthesis and crystal structure of a pentacopper(II) 12-metallacrown-4: cis-diaquatetrakis(dimethylformamide-κO)manganese(II) tetrakis(μ(3)-N,2-dioxidobenzene-1-carboximidate)pentacopper(II) dimethylformamide monosolvate
The title compound, [Mn(C(3)H(7)NO)(4)(H(2)O)(2)][Cu(5)(C(7)H(4)NO(3))(4)]·C(3)H(7)NO or cis-[Mn(H(2)O)(2)(DMF)(4)]{Cu[12-MC(Cu(II)N(shi))-4]}·DMF, where MC is metallacrown, shi(3−) is salicylhydroximate, and DMF is N,N-dimethylformamide, crystallizes in the monoclinic space group P2(1)/n. Two cr...
Autores principales: | Van Trieste III, Gerard P., Zeller, Matthias, Zaleski, Curtis M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199261/ https://www.ncbi.nlm.nih.gov/pubmed/32431945 http://dx.doi.org/10.1107/S2056989020005770 |
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