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Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate

The condensation of 2-furoic hydrazide and 4-dimethyl amino­benzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by inter­molecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two...

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Autores principales: Sylla-Gueye, Rokhaya, Thiam, Ibrahima Elhadji, Orton, James, Coles, Simon, Gaye, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199266/
https://www.ncbi.nlm.nih.gov/pubmed/32431928
http://dx.doi.org/10.1107/S205698902000465X
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author Sylla-Gueye, Rokhaya
Thiam, Ibrahima Elhadji
Orton, James
Coles, Simon
Gaye, Mohamed
author_facet Sylla-Gueye, Rokhaya
Thiam, Ibrahima Elhadji
Orton, James
Coles, Simon
Gaye, Mohamed
author_sort Sylla-Gueye, Rokhaya
collection PubMed
description The condensation of 2-furoic hydrazide and 4-dimethyl amino­benzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by inter­molecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C—H⋯O inter­actions link the mol­ecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety, i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes.
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spelling pubmed-71992662020-05-19 Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate Sylla-Gueye, Rokhaya Thiam, Ibrahima Elhadji Orton, James Coles, Simon Gaye, Mohamed Acta Crystallogr E Crystallogr Commun Research Communications The condensation of 2-furoic hydrazide and 4-dimethyl amino­benzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by inter­molecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C—H⋯O inter­actions link the mol­ecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety, i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes. International Union of Crystallography 2020-04-09 /pmc/articles/PMC7199266/ /pubmed/32431928 http://dx.doi.org/10.1107/S205698902000465X Text en © Sylla-Gueye et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Sylla-Gueye, Rokhaya
Thiam, Ibrahima Elhadji
Orton, James
Coles, Simon
Gaye, Mohamed
Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title_full Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title_fullStr Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title_full_unstemmed Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title_short Crystal structure of N′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
title_sort crystal structure of n′-[4-(di­methyl­amino)­benzyl­idene]furan-2-carbohydrazide monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199266/
https://www.ncbi.nlm.nih.gov/pubmed/32431928
http://dx.doi.org/10.1107/S205698902000465X
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