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Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate
The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by intermolecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199266/ https://www.ncbi.nlm.nih.gov/pubmed/32431928 http://dx.doi.org/10.1107/S205698902000465X |
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author | Sylla-Gueye, Rokhaya Thiam, Ibrahima Elhadji Orton, James Coles, Simon Gaye, Mohamed |
author_facet | Sylla-Gueye, Rokhaya Thiam, Ibrahima Elhadji Orton, James Coles, Simon Gaye, Mohamed |
author_sort | Sylla-Gueye, Rokhaya |
collection | PubMed |
description | The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by intermolecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C—H⋯O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety, i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes. |
format | Online Article Text |
id | pubmed-7199266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-71992662020-05-19 Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate Sylla-Gueye, Rokhaya Thiam, Ibrahima Elhadji Orton, James Coles, Simon Gaye, Mohamed Acta Crystallogr E Crystallogr Commun Research Communications The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C(14)H(15)N(3)O(2)·H(2)O. The crystal packing is stabilized by intermolecular O(water)—H⋯O,N(carbohydrazide) and N—H⋯O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C—H⋯O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety, i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes. International Union of Crystallography 2020-04-09 /pmc/articles/PMC7199266/ /pubmed/32431928 http://dx.doi.org/10.1107/S205698902000465X Text en © Sylla-Gueye et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Sylla-Gueye, Rokhaya Thiam, Ibrahima Elhadji Orton, James Coles, Simon Gaye, Mohamed Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title | Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title_full | Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title_fullStr | Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title_full_unstemmed | Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title_short | Crystal structure of N′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
title_sort | crystal structure of n′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199266/ https://www.ncbi.nlm.nih.gov/pubmed/32431928 http://dx.doi.org/10.1107/S205698902000465X |
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