Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl

Terbium oxychloride, TbOCl, was synthesized via the simple heat-treatment of TbCl(3)·6H(2)O and its structure was determined by refinement against X-ray powder diffraction data. TbOCl crystallizes with the matlockite (PbFCl) structure in the tetra­gonal space group P4/nmm and is composed of alternat...

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Autores principales: Chong, Saehwa, Riley, Brian J., Nelson, Zayne J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199267/
https://www.ncbi.nlm.nih.gov/pubmed/32431920
http://dx.doi.org/10.1107/S2056989020004387
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author Chong, Saehwa
Riley, Brian J.
Nelson, Zayne J.
author_facet Chong, Saehwa
Riley, Brian J.
Nelson, Zayne J.
author_sort Chong, Saehwa
collection PubMed
description Terbium oxychloride, TbOCl, was synthesized via the simple heat-treatment of TbCl(3)·6H(2)O and its structure was determined by refinement against X-ray powder diffraction data. TbOCl crystallizes with the matlockite (PbFCl) structure in the tetra­gonal space group P4/nmm and is composed of alternating (001) layers of (TbO)(n) and n Cl(−). The unit-cell parameters, unit-cell volume, and density were compared to the literature data of other isostructural rare-earth oxychlorides in the same space group and showed good agreement when compared to the calculated trendlines.
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spelling pubmed-71992672020-05-19 Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl Chong, Saehwa Riley, Brian J. Nelson, Zayne J. Acta Crystallogr E Crystallogr Commun Research Communications Terbium oxychloride, TbOCl, was synthesized via the simple heat-treatment of TbCl(3)·6H(2)O and its structure was determined by refinement against X-ray powder diffraction data. TbOCl crystallizes with the matlockite (PbFCl) structure in the tetra­gonal space group P4/nmm and is composed of alternating (001) layers of (TbO)(n) and n Cl(−). The unit-cell parameters, unit-cell volume, and density were compared to the literature data of other isostructural rare-earth oxychlorides in the same space group and showed good agreement when compared to the calculated trendlines. International Union of Crystallography 2020-04-03 /pmc/articles/PMC7199267/ /pubmed/32431920 http://dx.doi.org/10.1107/S2056989020004387 Text en © Chong et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Chong, Saehwa
Riley, Brian J.
Nelson, Zayne J.
Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title_full Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title_fullStr Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title_full_unstemmed Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title_short Dehydration synthesis and crystal structure of terbium oxychloride, TbOCl
title_sort dehydration synthesis and crystal structure of terbium oxychloride, tbocl
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199267/
https://www.ncbi.nlm.nih.gov/pubmed/32431920
http://dx.doi.org/10.1107/S2056989020004387
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