Synthesis and crystal structure of ABW-type SrFe(1.40)V(0.60)O(4)

Single crystals of SrFe(1.40)V(0.60)O(4), strontium tetra­oxidodi[ferrate(III)/vanad­ate(III)], have been obtained as a side product in the course of sinter experiments aimed at the synthesis of double perovskites in the system SrO–Fe(2)O(3)–V(2)O(5). The crystal structure can be characterized by la...

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Detalles Bibliográficos
Autores principales: Gstir, Thomas, Kahlenberg, Volker, Krüger, Hannes, Penner, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7199274/
https://www.ncbi.nlm.nih.gov/pubmed/32431929
http://dx.doi.org/10.1107/S205698902000496X
Descripción
Sumario:Single crystals of SrFe(1.40)V(0.60)O(4), strontium tetra­oxidodi[ferrate(III)/vanad­ate(III)], have been obtained as a side product in the course of sinter experiments aimed at the synthesis of double perovskites in the system SrO–Fe(2)O(3)–V(2)O(5). The crystal structure can be characterized by layers of six-membered rings of TO(4)-tetra­hedra (T: Fe(III), V(III)) perpendicular to [100]. Stacking of the layers along [100] results in a three-dimensional framework enclosing tunnel-like cavities in which Sr(II) cations are incorporated for charge compensation. The sequence of directedness of up (U) and down (D) pointing vertices of neighboring tetra­hedra in a single six-membered ring is UUUDDD. The topology of the tetra­hedral framework belongs to the zeolite-type ABW.

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