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Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules
The structure transformation of Mg-CUK-1 due to the confinement of H(2)O molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different H(2)O loadings and the cell parameters of the H(2)O-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements....
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7215401/ https://www.ncbi.nlm.nih.gov/pubmed/32295240 http://dx.doi.org/10.3390/ma13081840 |
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| author | Sánchez-González, Elí Flores, J. Gabriel Flores-Reyes, Julio C. Morales-Salazar, Ivette Blanco-Carapia, Roberto E. Rincón-Guevara, Mónica A. Islas-Jácome, Alejandro González-Zamora, Eduardo Aguilar-Pliego, Julia Ibarra, Ilich A. |
| author_facet | Sánchez-González, Elí Flores, J. Gabriel Flores-Reyes, Julio C. Morales-Salazar, Ivette Blanco-Carapia, Roberto E. Rincón-Guevara, Mónica A. Islas-Jácome, Alejandro González-Zamora, Eduardo Aguilar-Pliego, Julia Ibarra, Ilich A. |
| author_sort | Sánchez-González, Elí |
| collection | PubMed |
| description | The structure transformation of Mg-CUK-1 due to the confinement of H(2)O molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different H(2)O loadings and the cell parameters of the H(2)O-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements. A bottleneck effect was observed when one hydrogen-bonded H(2)O molecule per unit cell (18% relative humidity (RH)) was confined within Mg-CUK-1, confirming the increase in the CO(2) capture for Mg-CUK-1. |
| format | Online Article Text |
| id | pubmed-7215401 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-72154012020-05-18 Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules Sánchez-González, Elí Flores, J. Gabriel Flores-Reyes, Julio C. Morales-Salazar, Ivette Blanco-Carapia, Roberto E. Rincón-Guevara, Mónica A. Islas-Jácome, Alejandro González-Zamora, Eduardo Aguilar-Pliego, Julia Ibarra, Ilich A. Materials (Basel) Communication The structure transformation of Mg-CUK-1 due to the confinement of H(2)O molecules was investigated. Powder X-ray diffraction (PXRD) patterns were collected at different H(2)O loadings and the cell parameters of the H(2)O-loaded Mg-CUK-1 material were determined by the Le Bail strategy refinements. A bottleneck effect was observed when one hydrogen-bonded H(2)O molecule per unit cell (18% relative humidity (RH)) was confined within Mg-CUK-1, confirming the increase in the CO(2) capture for Mg-CUK-1. MDPI 2020-04-14 /pmc/articles/PMC7215401/ /pubmed/32295240 http://dx.doi.org/10.3390/ma13081840 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Communication Sánchez-González, Elí Flores, J. Gabriel Flores-Reyes, Julio C. Morales-Salazar, Ivette Blanco-Carapia, Roberto E. Rincón-Guevara, Mónica A. Islas-Jácome, Alejandro González-Zamora, Eduardo Aguilar-Pliego, Julia Ibarra, Ilich A. Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title | Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title_full | Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title_fullStr | Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title_full_unstemmed | Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title_short | Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H(2)O Molecules |
| title_sort | bottleneck effect explained by le bail refinements: structure transformation of mg-cuk-1 by confining h(2)o molecules |
| topic | Communication |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7215401/ https://www.ncbi.nlm.nih.gov/pubmed/32295240 http://dx.doi.org/10.3390/ma13081840 |
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